Yeah, the service file looks okay. I was just checking for errors on this and found this one that seems to be related. which version are you running?

https://github.com/bitcoin/bitcoin/issues/21699

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Check you messages I explain when I started having problems. I don't think it's my Ubuntu version.

I think I'm on 22.04.2 though

is the lnd service running?

Lnd won't run because it's dependent on Bitcoin core