If you use the Tor network no one can know what you are doing, neither can your ISP, only the Tor exit node knows what you are accessing but given Tor's onion layer system, the exit node also does not know where the packets are coming from and therefore who you are.

That said, spy agencies have used statistical methods to try to de-anonymize people behind tor, but to give you an idea, with the first version of tor that only used 3 hops and refused circuits, it took about 3 months to figure out a possible target, now tor changes circuits constantly including making 6 hops on certain occasions.