You can find out more on NWC here: https://habla.news/tony/zapplepay
While the guide is dedicated to ZapplePay, a part of it cover the NWC setup process.
nsecbunker: you sign events remotely, so client side you login with your npub. Read more https://lnshort.it/nsecbunker
Alby NWC: means nostr wallet connect, remotely sign transactions. To setup on kiwi is simply go to settings, choose NWC, sign first transaction will prompt for you to allow permission
You can find out more on NWC here: https://habla.news/tony/zapplepay
While the guide is dedicated to ZapplePay, a part of it cover the NWC setup process.