Gold is an inanimate object, as is green cotton.
Gold is not supposed to kill fiat - fiat's own contradictions will do that (and many, many fiat currencies have blown up over the past 50 years).
Imagine that fiat does in fact die. I think it's quite clear that material goods will retain trade value, and based on their scarcity & usefulness we can work out exchange ratios and rebuild an industrial economy. But what will determine the exchange ratio of Bitcoin to silver? To oil? To beef?