Well, 10002 events are not for storing configuration settings:

"The primary purpose of this relay list is to advertise to others, not for configuring one's client."

https://github.com/nostr-protocol/nips/blob/master/65.md

I reckon storing client settings should be done in a specific "list" (maybe a private list) as defined in NIP-51 (still a PR).

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Well, actually NIP-65 is not for storing client settings.

#[1]

You could use NIP-65 as your client's settings if you wanted them to match what you advertise. Or you might have a reason to use additional relays that you don't advertise to others, and store that information elsewhere, perhaps in a NIP-51.