I'm running GrapheneOS and can access via Brave:

Are you certain you installed the root CA?

https://docs.start9.com/0.3.4.x/guides/device-guides/dg-android/lan-android

You should see this under Settings > Security and Privacy > More security & privacy > Encryption & credentials > Trusted credentials (User tab):

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Discussion

I have it installed. Its fine on all other devices and worked fine when I was running CalyxOS on this device. I do get a DNS error in Brave when I try and connect to it.

Connecting apps and stuff to it work I just cant connect to the .local without TOR