Are you talking about ETFs? If so, I was always asking myself the same question. There's an interesting article from Jameson Lopp which addresses this issue of the effect of IOUs on Bitcoin's soundness: https://blog.casa.io/securing-bitcoins-scarcity/
As for zakat, sadaqah etc. We're generally tought to give from what we love most. And for me it's Bitcoin that I attribute the greatest value to. So ... 🤷♂️