They claim to have tested quicklime experimentally with a reasonable control, so I'm inclined to believe the ultimate conclusion

I am skeptical that the volcanic ash is not actually helpful (assuming the claims about its ancient use & reputation are accurate)

Perhaps both are relevant

Is there some other error in thinking you've found?

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I wouldn’t say absolutely, because that would be a flaw in my thinking.

But I am skeptical of the selective use of historical documentation.

They also claim to have proved that this was how the Romans did it, because their experiment achieved a similar result. It didn’t, they only proved they can achieve similar results using this method.

But there is something more I can’t quite put into words yet, that has been bothering me about the way western science and academia think about things.

Side note, this kinda feels like an advertisement for a patentable process they want to sell.