Yes, You can...

// MilliSatoshi are the native unit of the Lightning Network. A milli-satoshi

// is simply 1/1000th of a satoshi. There are 1000 milli-satoshis in a single

// satoshi. Within the network, all HTLC payments are denominated in

// milli-satoshis. As milli-satoshis aren't deliverable on the native

// blockchain, before settling to broadcasting, the values are rounded down to

// the nearest satoshi.

https://bitcoin.stackexchange.com/questions/69700/what-is-a-millisatoshi-i-thought-satoshi-is-the-smallest-unit

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double spending....

In the future, maybe it will be to spend 0.5 satoshi in one store and send the other 0.5 satoshi to someone.

99% of people think that satoshi is the smallest unit, LN has changed that a bit....