I'm... Not cloth savy, but I do know plastics pretty well. PE is a pain to paint without some kind of nasty stuff in the pigment carrier. I'm not sure most paints are going to want to stick-well enough long term.

I'd definitely get a cardboard tube and roll it instead of folding it to prevent the paint from cracking on joints.

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What's PE?

Could be polyethylene in some cases.

Polyester.