Citrus essential oils will melt their exoskeleton but you need enough to get to their hive.

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nostr:npub1ch07kghhfskej77c9v0k2yhcy0xzmx32dcgv265u2xvj9fw56xwqjalera neat! maybe mixed with water to not have to invest too much? got these effers in a raised bed so probably need a lot

Yes you would mix it with water. I am not sure of the ratio but you may need a good amount to get the queen. At the very least it will knock them back.

Here I a site with directions that you can modify as desired

https://www.barefeetonthedashboard.com/2015/04/how-to-kill-fire-ants-without-harsh-chemicals/#:~:text=Researches%20from%20Texas%20A%26M%20have,Victory