DC LED wiring is cool. It can technically be more efficient due to not having to do double conversions (DC from panels to battery to AC through an inverter, back to DC in the bulb), but...
No one should be doing 12V storage in a house. (Yes, that's a strong opinion.) Minimum: nominal 48V systems. Copper is too expensive and also most 48V system stuff is significantly more efficient and can be less expensive per watt. You'd at least need one DC to DC converter for the lighting, and unless you get something that's not bottom of the barrel, it might not be any more efficient than using regular bulbs via 120V.