Its water vapor

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I still don't get the how. A pan has a hot surface at the bottom and the water touching the bottom of the pan turns to steam, OK that's cool. The steam water molecules are moving so fast and with so much energy they push the water out of the way, but surely the gap that is created by the pushing is a vacuum no?

Theres no vacuum it expands a lot when it turns to gas (a bubble) then floats to the top