Android operating systems do provide an always on and leak blocking VPN functionality per-profile. We close out many more VPN leaks than the stock OS does too. Providing the app is well designed it should continue to stay running. Orbot was known to be terrible with this (tons of bugs) and had crashes on our exploit mitigations. If it ever got a recommendation then it only would have been because there was little other options.
The per-profile VPN helps segregate networks like this easily. You could run a VPN on a standard user and an anonymity network in the profile's Private Space and you can switch to both with ease.