If you're NIP 05 verified, then yes, it'll show on your pfp.
I have tried doing that a number of times with Alby, but it seems to not register. Or, do you see it?
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It is currently showing as being unhealthy, hence the red exclamation mark on your profile. Try registering your NIP 05 with a different client. NIP05.Social is where I did mine.
