They're refinery waste. To light them, either pour a lot of petroleum over them (not a particularly good idea), or with a lot of those waxed-cardboard lighting sticks. Pointing a leaf blower at it (low power mode) helps a lot.
Good tips for anyone who doesn't have a chimney starter
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the real tip is get a fucking chimney starter. i watched a video before and was like "ohhhhhhhhhhhh, shit. that's what i needed!"
Right. Forgot about these. They're great, too